Defect control in the Heisenberg-Kitaev candidate material <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>NaRuO</mml:mi><mml:mn>2</mml:mn></mml:msub></mml:math>

نویسندگان

چکیده

The combination of geometric frustration, extended hopping, spin-orbit coupling, and a disordered magnetic ground state make NaRuO$_{2}$ an attractive Heisenberg-Kitaev candidate material. Historically, NaRuO$_2$ has been challenging material to produce, even in polycrystalline form. Here we present synthetic efforts that identify propensity for Na$_\text{Ru}$ defects form NaRuO$_2$, revealing full solid-solution between Na$_2$RuO$_3$. We report the synthesis alloys along Na$_{3+x}$Ru$_{3-x}$O$_6$ solid solution characterize changes bulk magnetization electron transport as function Na-loading. Our results highlight importance stoichiometry control when investigating interpreting this material's physical properties.

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ژورنال

عنوان ژورنال: Physical Review Materials

سال: 2022

ISSN: ['2476-0455', '2475-9953']

DOI: https://doi.org/10.1103/physrevmaterials.6.104413